I have seen directions that say to hit it with campden tablet, wait for 24 hours, hit it with pectinase, wait another 24 hours, then pitch. So since it just finished having the heck boiled out of it, I'm pretty sure you're safe! If it's too hot to pitch, it's more than likely been warm enough for long enough to be considered pasteurized...
I regularly let things sit with pectinase for 24 hours, rarely do I bother with campden tablets except with unheated pears... they're the only thing I've worked with that seems to get funny while the pectinase is doing its thing. Well, that and fresh pressed apple juice, mine always has native yeasts starting to do their thing so if I want to use pectinase after I press it, I pretty much have to hit it with campden tabs or else the native yeasts take care of it before I even pitch! ...this is why I usually shred the apples and let them sit overnight with the pectinase and then press and pitch immediately.